Safety Measures

1. Information on basic physical and chemical properties
   a) Appearance Form: liquid, clear Colour: colourless
   b) Odour: sulphurous
   c) Odour Threshold: No data available
   d) pH: Not applicable
   e) Melting point/freezing point: Melting point/range: 18.4 °C
   f) Initial boiling point and boiling range: 189°C at 1,013 hPa
   g) Flash point: 87°C – closed cup – ASTM D 93
   h) Evaporation rate: No data available
   i) Flammability (solid, gas): No data available
   j) Upper/lower flammability or explosive limits: Upper explosion limit: 42 %(V) Lower explosion limit: 3.5 %(V
   k) Vapour pressure: 0.55 hPa at 20 °C, 4 hPa at 50 °C
   l) Vapour density: 2.70 – (Air = 1.0)
   m) Relative density: 1.104 g/cm3 at 20 °C
   n) Water solubility: completely miscible
   o) Partition coefficient: n-octanol/water: log Pow: -1.35
   p) Auto-ignition temperature: 300 – 302 °C
   q) Decomposition temperature: > 190 °C –
   r) Viscosity No data available
   s) Explosive properties Not explosive
   t) Oxidizing properties The substance or mixture is not classified as oxidizing.
2. Other safety information
   Solubility in other solvents: Alcohol – soluble Diethylether – soluble
   Surface tension: 43.5 mN/m at 20 °C
   Relative vapour density: 2.70 – (Air = 1.0)

1. Reactivity
   No data available
2. Chemical stability
   S
   table under recommended storage conditions.
3. Possibility of hazardous reactions
   No data available
4. Conditions to avoid
   Heat, flames and sparks.
5. Incompatible materials
   Acid chlorides, Phosphorus halides, Strong acids, Strong oxidizing agents, Strong reducing agents
6. Hazardous decomposition products
   Hazardous decomposition products formed under fire conditions. – Carbon oxides, Sulphur oxides
   Other decomposition products – No data available In the event of fire: see section 5

1. Information on toxicological effects
   Acute toxicity
   LD50 Oral – Rat – male and female – 28,300 mg/kg (OECD Test Guideline 401)
   LC0 Inhalation – Rat – male and female – 4 h – > 5.33 mg/l (OECD Test Guideline 403)
   LD50 Dermal – Rat – male and female – 40,000 mg/kg Remarks: (ECHA)
2. Skin corrosion/irritation
   Skin – Rabbit
   Result: slight irritation – 4 h (OECD Test Guideline 404)
3. Serious eye damage/eye irritation
   Eyes – Rabbit
   Result: slight irritation – 24 h
   (OECD Test Guideline 405)
4. Respiratory or skin sensitisation Maximisation Test – Guinea pig Result: negative
   (OECD Test Guideline 406)
   Local lymph node assay (LLNA) – Mouse Result: negative
   (OECD Test Guideline 429)
5. Germ cell mutagenicity
   Ames test
   Salmonella typhimurium Result: negative
   sister chromatid exchange assay Chinese hamster ovary cells Result: negative
   Mutagenicity (mammal cell test): chromosome aberration. Chinese hamster ovary cells
   Result: negative
   OECD Test Guideline 474 Rat – male and female Result: negative
6. Carcinogenicity
   IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
7. Reproductive toxicity
   No data available
8. Specific target organ toxicity – single exposure
   No data available
9. Specific target organ toxicity – repeated exposure
   No data available
10. Aspiration hazard
    No data available
11. Additional Information
    Repeated dose toxicity – Rat – male and female – Oral – 18 Months – No observed adverse effect level – 3,300 mg/kg – Lowest observed adverse effect level – 9,900 mg/kg
    Repeated dose toxicity – Monkey – male and female – Dermal – 18 Months – No observed adverse effect level – >= 8,910 mg/kg – Lowest observed adverse effect level – 990 mg/kg RTECS: PV6210000
    Exposure to large amounts can cause: redness of skin, Itching, burning, sedation, Headache, Nausea, Dizziness
    To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

1. Toxicity
   Toxicity to fish: static test LC50 – Danio rerio (zebra fish) – > 25,000 mg/l – 96 h
   Toxicity to daphnia and other aquatic invertebrates
   (OECD Test Guideline 203)
   static test EC50 – Daphnia magna (Water flea) – 24,600 mg/l – 48 h (OECD Test Guideline 202)
   Toxicity to algae static test ErC50 – Pseudokirchneriella subcapitata (green algae) – 17,000 mg/l – 72 h
   (OECD Test Guideline 201)
   Toxicity to bacteria EC50 – activated sludge – 10 – 100 mg/l – 30 min
   (ISO 8192)
2. Persistence and degradability
   Biodegradability aerobic – Exposure time 28 d
   Result: 31 % – Not readily biodegradable. (OECD Test Guideline 301D)
3. Bioaccumulative potential
   No data available
4. Mobility in soil
   No data available
5. Results of PBT and vPvB assessment
   This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
6. Other adverse effects
   No data available
7. Stability in water – 0.12 – 1.2 h at 30 °C
   Remarks: Hydrolyses readily.

1. Waste treatment methods
   Product
   Offer surplus and non-recyclable solutions to a licensed disposal company.
   Contaminated packaging
   Dispose of as unused product.

1. UN number
   ADR/RID: – IMDG: – IATA: –
2. UN proper shipping name
   ADR/RID: Not dangerous goods
   IMDG: Not dangerous goods
   IATA: Not dangerous goods
3. Transport hazard class(es)
   ADR/RID: – IMDG: – IATA: –
4. Packaging group
   ADR/RID: – IMDG: – IATA: –
5. Environmental hazards
   ADR/RID: no IMDG Marine pollutant: no IATA: no
6. Special precautions for user
   No data available

1. Safety, health and environmental regulations/legislation specific for the substance or mixture
   This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
2. Chemical safety assessment
   For this product a chemical safety assessment was not carried out

Further information

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The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. ETRA Organics and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See www.etraorganics.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

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